TRIBOLOGICAL BEHAVIOR OF PVD AND ELECTROPLATED AIRCRAFT COATINGS
DOI:
https://doi.org/10.18372/0370-2197.3(112).21626Keywords:
titanium alloy VT-22, vacuum-arc PVD coatings, electroplated chromium, molybdenum coating, sliding wear, AMG-10 hydraulic fluid, adhesive wear, substrate effectAbstract
This paper investigates the tribological behavior in sliding friction and the wear resistance of cathodic vacuum-arc (PVD) and electroplated coatings deposited onto high-strength titanium alloy VT-22 and structural steel VKS-170. The relevance of the study is driven by the urgent need to replace environmentally hazardous hard chrome plating with vacuum-arc PVD alternatives, as well as to overcome the high tendency of titanium alloys toward adhesive seizure and galling in aerospace friction units. Face-sliding friction tests were conducted in an AMG-10 aviation hydraulic fluid medium against an AISI 1045 steel counterbody (45–50 HRC). The investigated surface systems included electroplated hard chromium, cathodic vacuum-arc coatings of hard chromium, soft chromium, and molybdenum, as well as uncoated base materials. The experimental findings demonstrate that electroplated chromium exhibits the lowest wear rate. Among the vacuum-arc deposits, hard chromium and molybdenum demonstrate high wear resistance on the VT-22 alloy, which, coupled with exceptional adhesion strength, positions them as viable, eco-friendly substitutes for galvanic chrome plating. Conversely, soft PVD chromium showed poor durability due to a porous columnar microstructure. Uncoated VT-22 suffered catastrophic adhesive seizure driven by localized microwelding and lubricant film breakdown. Additionally, a pronounced substrate (eggshell) effect was identified: the higher elastic compliance of VT-22 increased stress concentrations within thin functional layers, yielding 30–50% higher wear than on the stiffer VKS-170 steel. Practical recommendations are formulated for applying thick PVD coatings in aerospace pivot joints and plain bearings.
References
1. Inagaki I., Takechi T., Shirai Y., Ariyasu N. Application and Features of Titanium for the Aerospace Industry. Nippon Steel & Sumitomo Metal Technical Report. 2014. No. 106. P. 22–27.
2. Zheng Y., Dong Y., Zhao S., Wang Z., Liu L. High-strength beta titanium alloys for aerospace applications: Microstructure and mechanical properties. Materials Science and Engineering: A. 2021. Vol. 823. Art. 141753. DOI: 10.1016/j.msea.2021.141753.
3. Zhang X., Dong H., Bell T., Li X. Friction and wear behavior of titanium alloys modified by modern surface engineering technologies: A review. Tribology International. 2021. Vol. 160. Art. 107048. DOI: 10.1016/j.triboint.2021.107048.
4. Qin W., Kang J., Yue W., Zhu L., Fu Z. Tribological behavior and wear mechanisms of Ti-6Al-4V alloy at elevated temperatures. Wear. 2020. Vol. 450–451. Art. 203256. DOI: 10.1016/j.wear.2020.203256.
5. Legg K., Graham M., Sartwell B. Sustainable alternatives for hexavalent hard chrome plating in aviation: A ten-year review of industrial transitions. Surface and Coatings Technology. 2019. Vol. 357. P. 1118–1127. DOI: 10.1016/j.surfcoat.2018.10.052.
6. Tillmann W., Grisales D., Stangier D., Thomann C. A. Mechanical and tribological performance of eco-friendly PVD coatings replacing hard chromium. Surface and Coatings Technology. 2020. Vol. 399. Art. 126135. DOI: 10.1016/j.surfcoat.2020.126135.
7. Boxman R. L., Zhitomirsky V. N. Vacuum arc deposition of coatings: Innovations and modern trends in industrial applications. Plasma Sources Science and Technology. 2020. Vol. 29, No. 11. Art. 113001. DOI: 10.1088/1361-6595/abb4cb.
8. Anders A. Perspectives on cathodic arc deposition: Progress in ion energy control and plasma filtering. Applied Surface Science Advances. 2021. Vol. 6. Art. 100143. DOI: 10.1016/j.apsadv.2021.100143.
9. Wang Q., Zhou F., Zhou Z., Yan J. Wear mechanisms and interface bonding of thick cathodic arc PVD coatings on soft metallic substrates. Surface and Coatings Technology. 2022. Vol. 434. Art. 128189. DOI: 10.1016/j.surfcoat.2022.128189.
10. Leyland A., Matthews A. Design criteria for wear-resistant nanostructured and nanocomposite PVD coatings: Re-evaluating the H/E and H3/E2 metrics. Surface and Coatings Technology. 2022. Vol. 437. Art. 128368. DOI: 10.1016/j.surfcoat.2022.128368.
11. Bondarev A., Polcar T., Voevodin A. A. Tribological adaptation and lubricious Magnéli phase oxide formation in high-temperature sliding contacts of transition metal coatings. Tribology International. 2020. Vol. 147. Art. 106292. DOI: 10.1016/j.triboint.2020.106292.
12. Pohreliuk I. M., Fedirko V. M., Tkachuk O. V., Proskurniak R. V. Znosostiikist tytanovoho splavu VT22 pislia termodyfuziinoho azotuvannia. Fizyko-khimichna mekhanika materialiv. 2012. T. 48, № 4. S. 98–104.
13. Fedirko V. M., Pohreliuk I. M. Nitrydni i oksydni pokryttia na tytani ta yoho splavakh. Kyiv: Naukova dumka, 2004. 224 s.
14. Yakobchuk O. Ye. Znosostiikist vakuumno-duhovykh ta halvanichnykh pokryttiv v umovakh tertia kovzannia. Problemy tertia ta znoshuvannia. 2011. Vyp. 56. S. 190–195. DOI: 10.18372/0370-2197.56.3488.
15. Khimko А. M., Kralya V. O., Yakobchyk O. Y., Khomenko M. S. Wear Resistance of Materials Under Reversal and One-Directed Friction Sliding. Вісник Національного авіаційного університету. 2011. № 1 (46). С. 96–100. DOI: 10.18372/2306-1472.46.2088.
16. Al-Quraan T. M. A., Mikosianchyk O., Yakobchuk O., Mnatsakanov R., Khimko A., Kostiunik R. The effect of water on the tribological properties of aviation lubricants. Tribology in Industry. 2025. Vol. 47, No. 3. P. 513–525. DOI: 10.24874/ti.1971.06.25.08.
17. Al-Quraan T. M. A., Khimko A., Khimko M., Mikosianchyk O., Mnatsakanov R., Yakobchuk O. Increasing the Wear Resistance of Titanium Alloys in Plain Bearings with Galvanic and Vacuum-Arc Coatings. Tribology in Industry. 2026. Vol. 48, No. 1. P. 72–82. DOI: 10.24874/ti.2043.10.25.11.
Downloads
Published
How to Cite
Issue
Section
License

This work is licensed under a Creative Commons Attribution 4.0 International License.
The scientific journal adheres to the principles of Open Access and provides free, immediate, and permanent access to all published materials without financial, technical, or legal barriers for readers.
All articles are published in Open Access under the Creative Commons Attribution 4.0 International (CC BY 4.0) license.
Copyright
Authors who publish their works in the journal “Problems of Friction and Wear”:
-
retain the copyright to their publications;
-
grant the journal the right of first publication of the article;
-
agree to the distribution of their materials under the CC BY 4.0 license;
-
have the right to reuse, archive, and distribute their works (including in institutional and subject repositories), provided that proper reference is made to the original publication in the journal.



