THE THERMODYNAIC PROPERTIES OF MELTS OF THE SYSTEM MgO – Al2O3 – SiO2, MgO – CaF2 – SiO2, Al2O3 – CaF2 – SiO2
DOI:
https://doi.org/10.18372/2306-1472.48.65Abstract
Abstract. Method of forecasting thermodynamic properties of melts from the liquidus coordinates ofphase diagram in the area of equilibrium of a solid component with a solution is presented. Gibbs mixingenergies in the binary boundary MgO – Al2O3, MgO – SiO2, MgO – CaF2, Al2O3 – SiO2, Al2O3 – CaF2,SiO2 – CaF2 systems are calculated by this method.Keywords: a activity, coordinates of liquidus, the diagrams of the state, the double and triple systems, theequalization of Hauffe-Wagner, the melts, the partial molar energy of Gibbs, the thermodynamics properties.References
Судавцова, В.С.; Макара, В.А.; Кудін, В.Г.
Термодинаміка металургійних і зварювальних
розплавів. Ч. 3. Сплави на основі нікелю та
олова, методи моделювання та прогнозування
термодинамічних властивостей. - Київ, 2005. –
с.
[Sudavtsova, V.S.; Makara, V.A.; Kudin, V.G.
Thermodynamic of metallurgical and welding
alloys. Part 3. Nickel and tin alloys, methods of
modeling and forecasting thermodynamic properties.
Kiev. 211 p.] (in Russian).
Шорников, С.И. Термодинамические
свойства расплавов системы MgO – SiO2 //
Вестник Отделения наук о Земле РАН. – 2006. –
№ 1 (24). – С. 230–234.
[Shornikov, S.I. 2006. Thermodynamic properties
of melts of the MgO – SiO2 system. Herald of
Department of the Earth Sciences Russian Academy
of Sciences. N 1 (24): 230–234.] (in Russian).
Шорников, С.И. Термодинамические
свойства расплавов системы Al2O3 – SiO2 //
Вестник Отделения наук о Земле РАН. – 2004. –
№ 1 (22). – С. 189–192.
[Shornikov, S.I. 2004. Thermodynamic properties
of melts of the Al2O3 – SiO2 system. Herald of
Department of the Earth Sciences Russian Academy
of Sciences. N 1 (22): 189–192.] (in Russian).
In-Ho, Jung; Decterov, S.A.; Pelton, A.D.
Critical thermodynamic evaluation an
optimization of the MgO – Al2O3, CaO – MgO –
Al2O3, and MgO – Al2O3 – SiO2 systems. Journal of
Phase Equilibria and Diffusion. Vol. 25, N 4:
–345.